How are phosphazenes made?


How are phosphazenes made?

Phosphazenes, which are cyclic or linear chain inorganic compounds formed by the bonding and repetition of phosphorus and nitrogen atoms with (P=N)n bonds, comprise an important class of inorganic compounds (Figure 1).2018-09-26

What are uses of Phosphazenes?

Poly[(organo)phosphazenes] are a unique class of extremely versatile polymers with a range of applications including tissue engineering and drug delivery, as hydrogels, shape memory polymers and as stimuli responsive materials.

What is phosphazene explain the nature of bonds in Triphosphazene?

The bonds between the phosphorus and nitrogen in phosphazenes are best described as having a significant ionic component with each of the N atoms having a negative charge and each of the phosphorus atoms having a positive charge.2019-07-22

What are inorganic polymers explain?

An inorganic polymer is a polymer with a skeletal structure that does not include carbon atoms in the backbone. Polymers containing inorganic and organic components are sometimes called hybrid polymers, and most so-called inorganic polymers are hybrid polymers.

What are Polyphosphazene used for?

Polyphosphazenes are polymers containing nitrogen as part of their backbone; they are commonly used in O-rings, pipelines, and seals in oil, fuel delivery, and storage systems.

What is inorganic rubber explain?

It was first observed in the late 19th century and its form after chain cross-linking has been called “inorganic rubber” due to its elastomeric behaviour. This polydichlorophosphazene product is the starting material for a wide class of polymeric compounds, collectively known as polyphosphazenes.

What is inorganic rubber?

into an amorphous substance which is insoluble and infusible, and whose mechanical properties are similar to those of rubber. It is, for this reason, generally known as inorganic rubber.

What are the 4 examples of inorganic molecules?

In general, there are four groups of inorganic compound types. They are divided into bases, acids, salts, and water. Note that these are the broadest categories of inorganic compounds.

What is inorganic polymer with example?

Examples of inorganic polymers include polysilanes (Si–Si bonds), polysiloxanes (Si–O bonds, or silicones), polysilazanes (Si–N bonds), polysulfides (S–S bonds), polyphosphazenes (P–N bonds), polyborazylenes (B–N bonds), and polythiazyls (S–N bonds).

Is rubber an inorganic compound?

Rubber, also called India rubber, latex, Amazonian rubber, caucho, or caoutchouc, as initially produced, consists of polymers of the organic compound isoprene, with minor impurities of other organic compounds.

What is the difference between organic and inorganic polymers?

Polymers are mainly in two types as organic polymers and inorganic polymers. The difference between organic and inorganic polymers is that the organic polymers essentially contain carbon atoms in the backbone whereas the inorganic polymers do not contain carbon atoms in the backbone.2018-07-12

What do you mean by phosphazene?

Phosphazenes refer to classes of organophosphorus compounds featuring phosphorus(V) with a double bond between P and N. One class of phosphazenes have the formula RN=P(NR2)3. These phosphazenes are also known as iminophosphoranes and phosphine imides. They are superbases.

What is the formula of phosphazene?

Phosphazenes refer to classes of organophosphorus compounds featuring phosphorus(V) with a double bond between P and N. One class of phosphazenes have the formula RN=P(NR2)3. These phosphazenes are also known as iminophosphoranes and phosphine imides.

What is considered inorganic material?

Inorganic materials are defined as chemical compounds that contain no carbon (C). However, elementary carbon (C) (as graphite or diamond) and compounds of carbon and, for example, nitrogen, oxygen, or silicon are also classified as inorganic.

Why Phosphonitrile are known as Phosphazenes?

Answer. *Phosphazenes are a class of chemical compounds in which a phosphorus atom is covalently linked to a nitrogen atom by a double bond and to three other atoms or radicals by single bonds. *Phosphazenes are also knownas iminophosphoranes and phosphonitriclic imides. The corresponding polymers are polyphosphazenes.2018-09-28

What are 5 examples of inorganic?

Examples of common everyday inorganic compounds are water, sodium chloride (salt), sodium bicarbonate (baking soda), calcium carbonate (dietary calcium source), and muriatic acid (industrial-grade hydrochloric acid). Inorganic compounds typically have high melting points and variable degrees of electrical conductivity.

What is phosphazene system?

Phosphazenes, which are cyclic or linear chain inorganic compounds formed by the bonding and repetition of phosphorus and nitrogen atoms with (P=N)n bonds, comprise an important class of inorganic compounds (Figure 1). There are many phosphazene compounds ranging from oligomers to polymers.2018-09-26

What is an example of inorganic material?

Introduction. Inorganic materials are defined as chemical compounds that contain no carbon (C). However, elementary carbon (C) (as graphite or diamond) and compounds of carbon and, for example, nitrogen, oxygen, or silicon are also classified as inorganic.

Phosphonitrilic chloride trimer | (NPCl2)3 – PubChem

Phosphonitrilic chloride trimer | (NPCl2)3 – PubChem compound Summary Phosphonitrilic chloride trimer Contents 1 Structures 2 Names and Identifiers 3 Chemical and Physical Properties 4 Spectral Information 5 Related Records 6 Chemical Vendors 7 Use and Manufacturing 8 Safety and Hazards 9 Literature 10 Patents 11 Biological Test Results

Phosphonitrilic chloride trimer 99 940-71-6

Phosphonitrilic chloride trimer 99%; CAS Number: 940-71-6; EC Number: 213-376-8; Synonyms: 1,3,5-Triaza-2,4,6-triphosphorin-2,2,4,4,6,6-hexachloride

Phosphonitrilic chloride trimer – 1,3 – Sigma-Aldrich

Phosphonitrilic chloride trimer. (NPCl2)3. Synonyms: 1,3,5-Triaza-2,4,6-triphosphorin-2,2,4,4,6,6-hexachloride, Hexachlorocyclotriphosphazene, 1,3,5,2,4,6

Phosphonitrilic Chloride Trimer 940-71-6 | TCI AMERICA

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Phosphonitrilic chloride trimer, 98%, ACROS Organics

Phosphonitrilic chloride trimer: Show More Show Less: Safety and Handling GHS H Statement Causes severe skin burns and eye damage. Reacts violently with water. GHS P Statement IF SWALLOWED: rinse mouth. Do NOT induce vomiting. Wear eye protection/face protection.

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Phosphonitrilic chloride trimer ≥98.5% | VWR

CAS: 940-71-6 MDL: MFCD00006474 Synonyms: Hexachlorocyclotriphosphazene, Cyclic Phosphonitrilic Chloride Trimer Phosphine

SAFETY DATA SHEET – Fisher Sci

Phosphonitrilic chloride trimerRevision Date 19-Jan-2018 be investigated: Ingestion causes severe swelling, severe damage to the delicate tissue and danger of perforation Notes to PhysicianTreat symptomatically 5. Fire-fighting measures Suitable Extinguishing MediaCO2, dry chemical, dry sand, alcohol-resistant foam.

TCI AMERICAS Phosphonitrilic chloride trimer: 940-71-6, F

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PDF Polyphosphonitrilic Chloride – pslc

Phosphonitrilic chloride trimer is ground in a mortar and pestle with ammonium persulfate in a ratio of 100 g of trimer to 2 g of persulfate (mole ratio = 2.87:0.0875, Note 1) to give an intimate mixture of the two compounds. Four grams of the mixture is sealed under vacuum in a 10 mm diameter glass tube 10-15 cm long (Note 2), and the tube is

Hexachlorophosphazene – Wikipedia

The molecule has a cyclic, unsaturated backbone consisting of alternating phosphorus and nitrogen centers, and can be viewed as a trimer of the hypothetical compound N≡PCl 2. Its classification as a phosphazene highlights its relationship to benzene.

Phosphonitrilic chloride trimer CAS#940-71-6 – High

Synonyms: Hexachlorotriphosphazene CAS NO.: 940-71-6 EINECS: 213-376-8 MF: Cl6N3P3 MW: 347.66 APPEARANCE White crystalline powder PURITY (GC) ≥99.0% MELTING POINT (℃) 110~115 LOSS ON DRYING ≤0.5% INSOLUBLE SUBSTANCE ≤0.1% English Name:Hexachlorocyclotriphosphazene;Phosphonitrilic chloride trimer CAS No.:940-71-6 Appearance:White crystalMelting Point:112-115 ℃, Density:1.98g/cm3

Phosphonitrilic chloride trimer supplier | CasNO.940-71-6

Phosphonitrilic chloride trimer Production The reaction of PCl 5 and NH 4 Cl affords substances with the empirical formula PNCl 2 : Purification by sublimation gives mainly the trimer (PNCl 2 ) 3 and tetramer (PNCl 2 ) 4 .

940-71-6 – Phosphonitrilic chloride trimer, 98%

A18986 Phosphonitrilic chloride trimer, 98% . CAS Number. 940-71-6. Synonyms Hexachlorocyclotriphosphazene. SDS Certificate of Analysis Product Specification Technical Inquiry Stock No. Size Price ($) Quantity Availability; A18986-14: 25g: 77.30: A18986-22: 100g: 216.00: Add

Phosphonitrilic chloride trimer | CAS#:940-71-6 | Chemsrc

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phosphonitrilic chloride trimer cas 940-71-6 – Haihang

Phosphonitrilic chloride trimerTypical Properties Phosphonitrilic chloride trimerUses Due to the active nature of the phosphorus-chlorine bond, chlorine can be easily substituted to form a series of phosphazene derivatives with special properties.

Phosphonitrilic chloride trimer(940-71-6) – LookChem

Phosphonitrilic chloride trimer (Cas:940-71-6) Factory Factory Direct Sales. CAS No: 940-71-6. Product Name: Phosphonitrilic chloride trimer. Purity: 97% ; 99%. Package: 25 kg or 50 kg cardboard drum, inside plastic bag vacuum packaging, or as specified by the customer;waterproof;. Supply Capacity: 10Ton / Per Month;. Price: Detailed.

940-71-6 | Phosphononitrilic Chloride Trimer | 2,2,4,4,6,6

Toronto Research Chemicals 20 Martin Ross Avenue Toronto, ON Canada, M3J 2K8 International: +1 (416) 665-9696 US & Canada: +1 (800) 727-9240 Email: [email protected] TRC is a subsidiary of LGC Standards

Phosphonitrilic chloride trimer – ResearchGate

The phosphonitrilic chlorides easily undergo nucleophilic substitution reactions. However, an effort to prepare triphosphonitrilic benzoate by a solid phase reaction of (NPCl2)3 with sodium

New Reactions of Phosphonitrilic Chloride Trimer

New Reactions of Phosphonitrilic Chloride Trimer. Substitution and Cleavage Reactions with Catechol and Triethylamine. H. R. Allcock

The Structure of the Trimer of Phosphonitrile Chloride

phosphonitrilic compounds: part i. the mechanism of phosphonitrilic chloride polymerization capacitance, conductance, and electron-spin resonance studies. Canadian Journal of Chemistry 1964 , 42 (2) , 447-455.

Phosphonitrilic chloride: 23. Substitution reaction of

Chlorine substitution reactions of phosphonitrilic chloride trimer (PNCl 2) 3 with 2-, 3- or 4- HOH 2 CC 6 H 4 ONa and 2-NaOH 2 CC 6 H 4 ONa were carried out in dioxane solvent under various experimental conditions. All reactions were completed in 40-200 min in the temperature range 60° to 100°C.

AddexBio Product Detail – Phosphonitrilic chloride trimer

Synomyms: Cyclic phosphonitrilic chloride trimer Technical Data: CAS No.: 940-71-6 M.Wt: MW:347.66 MDL Number: MFCD00006474 Formula: Cl 6 N 3 P 3 UN Number: UN 3260 Purity: >≥97% Appearance: White crystals?crystalline powder or chunks Density: N/A Melting Point: 112-115 °C(lit.) Optical Rotation: N/A Storage: Moisture sensitive/Ar

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Lowest price Phosphonitrilic Chloride Trimer CAS 940-71-6. Industrial Grade / 99.9%. $5-6 /KG FOB. Shanghai yunao International Trade Co., Ltd. Big discount Phosphonitrilic Chloride Trimer CAS 940-71-6. Industrial Grade / 99.9%. $5-6 /KG FOB

Phosphonitrilic chloride trimer purification

Polymer-grade cyclic phosphonitrilic chloride trimer can be obtained from crude cyclic polyphosphonitrilic chlorides by forming a solution of the crude cyclics, water washing the solution, distilling solvent to form a hot concentrate, cooling to form a precipitate and distilling the precipitate to form polymer-grade trimer.

Phosphonitrilic chloride trimer, CAS No. 940-71-6 – iChemical

See prices and buy Phosphonitrilic chloride trimer, CAS no. 940-71-6. Request custom packages or custom synthesis to facilitate your lab research.

Reactions of the trimer of phosphonitrile chloride

Replacement of the chlorine atoms of the trimer of phosphonitrile chloride by piperidine has yielded derivatives with a degree of replacement ranging from one to six chlorine atoms. In the case of the replacement of two and four chlorine atoms, isomeric di- and tetrapiperidino derivatives of the trimer of phosphonitrile chloride have been isolated.

Material Safety Data Sheet – Fisher Sci

OSHA Vacated PELs: Phosphonitrilic chloride, trimer: No OSHA Vacated PELs are listed for this chemical. Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA’s eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.

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Phosphonitrilic chloride trimer | 940-71-6-Molbase

Phosphonitrilic chloride trimer | 940-71-6 Cl6N3P3 structure,synthetic routes, physical and chemical properties, safety information, toxicity, customs data,maps, MSDS, generation methods and uses, and Phosphonitrilic chloride trimer’supstream and downstream products.

Phosphonitrilic Chloride Trimer Prices,Sales – buy

Description About Phosphonitrilic Chloride Trimer Cas 940-71-6 It is an intermediate raw material for the synthesis of various halogen-free flame retardants and high temperature resistant materials, such as the preparation of flame retardants such as phenoxy phosphazene, p-carboxy phenoxy phosphazene, polyamino phosphazene, and alkoxy phosphazene.

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Phosphonitrilic Chloride Trimer 940-71-6 | TCI Chemicals

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Phosphonitrilic chloride trimer (CAS No. 940-71-6

Suppliers List, E-mail/RFQ Form, Molecular Structure, Weight, Formula, IUPAC, Synonyms for Phosphonitrilic chloride trimer (CAS No. 940-71-6) Skype. Phosphonitrilic chloride trimer (CAS No. 940-71-6) Suppliers. Limit companies to: Worldwide USA China India

Safety Data Sheet

Phosphonitrilic chloride trimer Revision Date 24-December-2021 10. Stability and reactivity Reactive Hazard Yes Stability Moisture sensitive. Conditions to Avoid Exposure to moist air or water. Incompatible Materials Strong oxidizing agents, Alcohols, Amines, Bases Hazardous Decomposition ProductsNitrogen oxides (NOx), Phosphorus trihydride (phosphine), Thermal decomposition can

Diisothiocyanatophosphonitrilic Chloride Trimer and its

Diisothiocyanatophosphonitrilic chloride trimer has been prepared by the reaction of a stoichiometric quantity of ammonium thiocyanate with phosphonitrilic chloride

Phosphonitrilic chloride trimer purification – Ethyl

The high molecular weight linear phosphonitrilic chloride polymers used to make the various substituted polyphosphazenes can be made by the thermal polymerization of cyclic phosphonitrilic chloride trimer (referred to herein as “trimer”), preferably using a catalyst as described in U.S. Pat. Nos. 4,123,503 and 4,226,840.

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Phosphonitrilic chloride trimer, 98%, Thermo Scientific

Phosphonitrilic chloride trimer; Signal Word. Danger; Hazard Category. Serious eye damage/eye irritation Category 1; Skin corrosion/irritation Category 1 B; Hazard Statement. H318-Causes serious eye damage. H314-Causes severe skin burns and eye damage. EUH014-Reacts violently with water. Precautionary Statement

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CN104788495A – Fluorination method for phosphonitrilic

The invention relates to a fluorination method for phosphonitrilic chloride trimer and derivatives thereof. The fluorination method is characterized by taking phosphonitrilicchloride or partially substituted phosphonitrilic chloride trimer as a raw material, and adding a fluorating agent into an ionic liquid for fluorination so as to substitute chlorine in phosphonitrilic chloride trimer.

US Patent for Phosphonitrilic chloride trimer purification

Polymer-grade cyclic phosphonitrilic chloride trimer can be obtained from crude cyclic polyphosphonitrilic chlorides by forming a solution of the crude cyclics, water washing the solution, distilling solvent to form a hot concentrate, cooling to form a precipitate and distilling the precipitate to form polymer-grade trimer.

Phosphonitrilic chloride trimer | CAS 940-71-6 | SCBT

Phosphonitrilic chloride trimer is a a ring-opening polymerization, ligand and/or ligand precursor for transition metals. It is also a reagent for spherical dendrimers. 参考文献. 1. Labarre, J-F. et al., The saga of the design and synthesis of dandelion dendrimers Synlett, 799, (1996) 2. Chandrasekhar, V. et al. Inorg.

Bonding in phosphonitrilic chloride trimer: electron spin

Bonding in phosphonitrilic chloride trimer: electron spin resonance evidence for the radical anion . Shuddhodan P. Mishra and Martyn C. R. Symons Abstract. The e.s.r. spectrum for γ-irradiated hexachloro-cyclotriphosphazene

Phosphonitrilic Chloride Trimer CAS 940-71-6 98% Factory

Phosphonitrilic chloride trimer is high chlorine consuming product that is used as insecticide, fertilizer, antineoplastic drug, phase transfer catalyst, free radical polymerization initiator, light stabilizer, antioxidant, flame retardant. It is widely used in organic/inorganic high polymer materials, catalytic materials, high-temperature

China Phosphonitrilic chloride trimer

Product Description Phosphonitrilic chloride trimer CAS Item Specifications Results Appearance white crystalline powder Up to standard Purity 99.0(min) 99.45 Melting point 110~115.6 Loss on drying ≤0.5 0.19 Insoluble substance ≤0.1 0.09 Conclusion The results conforms with ente

New Reactions of Phosphonitrilic Chloride Trimer

New Reactions of Phosphonitrilic Chloride Trimer. Substitution and Cleavage Reactions with Catechol and Triethylamine. / Allcock, H. R. In: Journal of the American Chemical Society, Vol. 85, No. 24, 01.12.1963, p. 4050-4051. Research output: Contribution to journal › Letter › peer-review

940-71-6 Phosphonitrilic chloride trimer, tech. AKSci 0035TG

Phosphonitrilic chloride trimer, tech. 940-71-6 from AK Scientific, in San Francisco, California

Phosphonitrilic chloride trimer 98% | VWR

CAS: 940-71-6 MDL: MFCD00006474 EINECS: 213-376-8 Synonyms: Hexachlorocyclotriphosphazene, Cyclic Phosphonitrilic Chloride Trimer

Synthesis and ethylene oligomerization behavior of

Synthesis and characterization. PD-(NH 2) 6 was synthesized by reacting phosphonitrilic chloride trimer with 4-acetamidopheno via the substitution reaction and the hydrolysis reaction (Scheme1).In order to obtain the PD-(NH 2) 6 and its corresponding nickel complex with the high yield and the high purity, potassium carbonate (K 2 CO 3) as catalyst and acid binding agent and the excessive

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Phosphonitrilic chloride trimer – chembk.com

Product Name: Phosphonitrilic chloride trimer PREMIUM PRODUCT CAS : 940-71-6 Tel: 0086-551-65418679 Email: [email protected] [email protected] Mobile: 0086 158 5698 8503 QQ :2885216886 Wechat: 0086 189 4982 3763 WhatsApp: 0086 189 4982 3763

940-71-6 Phosphonitrilic chloride trimer AKSci J52909

Phosphonitrilic chloride trimer 940-71-6 from AK Scientific, in San Francisco, California

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Polymerization of phosphonitrilic chloride trimer at high

Polymerization of phosphonitrilic chloride trimer at pressures of 10 kbars and above has shown that increasing pressure favors the formation of the rubbery high polymer thermodynamically, but slows its rate of formation. There appears to be no difference in hydrolytic or thermal stability between elastomer formed under high pressure conditions

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1,3,5,2,4,6-Triazatriphosphorine, 2,2,4,4,6,6 – NIST

1,3,5,2,4,6-Triazatriphosphorine, 2,2,4,4,6,6-hexachloro-2,2,4,4,6,6-hexahydro-. Formula: Cl 6 N 3 P 3. Molecular weight: 347.659. IUPAC Standard InChI: InChI=1S/Cl6N3P3/c1-10 (2)7-11 (3,4)9-12 (5,6)8-10. Copy Sheet of paper on top of another sheet. IUPAC Standard InChIKey: UBIJTWDKTYCPMQ-UHFFFAOYSA-N. Copy Sheet of paper on top of another sheet.

Elastic and thermoelastic properties of "inorganic rubber

Polymerization of cyclic phosphonitrilic chloride trimer was carried out at sufficiently high temperatures and for sufficiently long periods to cause …

Hexachlorphosphazen

Hexachlorphosphazen oder Phosphornitrilchlorid-Trimer (NPCl 2-Trimer) ist eine anorganische Verbindung, die als sechsgliedriger Ring mit alternierenden Phosphor- und Stickstoffatomen mit der Summenformel (NPCl 2) 3 vorliegt.

A nitrogen and phosphorus enriched pyridine bridged

A new class of N- and P-enriched pyridine bridged inorganic-organic hybrid material is synthesized via the condensation of phosphonitrilic chloride trimer and 2,6-diaminopyridine at 140 °C for 18 h. It was used as the active electrode material for supercapacitor application. The role of mass loading on the o

China Phosphonitrilic Chloride Trimer Manufacturer

Phosphonitrilic Chloride Trimer, Hexachlorotriphosphazene, Hexachloride, Phosphonitrilic Chloride Trimer 1 3 5-Tr, Flame Retardant, Intermediate Company Introduction Zibo Lanyin Chemical Co., Ltd., located in the economic and technological development zone of Shangdong ZiBo city.

cas 139-02-6, Phenol, sodium salt(1:1) | Articles data

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940-71-6 | Phosphonitrilic chloride trimer – Capot Chemical

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Nitride chloride – Wikipedia

A chloride nitride is a mixed anion compound containing both chloride (Cl −) and nitride ions (N 3−).Another name is metallochloronitrides.They are a subclass of halide nitrides or pnictide halides.. The group 4 element chloride nitrides can be intercallated by alkali metals that supply extra electrons, and other molecules such as from solvents like tetrahydrofuran, yielding layered

Hexachlorotriphosphazene

Product Name: Phosphonitrilic chloride trimer PREMIUM PRODUCT CAS : 940-71-6 Tel: 0086-551-65418679 Email: [email protected] [email protected] Mobile: 15856988503 QQ :2885216886 Wechat: 0086 189 4982 3763 WhatsApp: 0086 189 4982 3763

Ali ELHAMPOUR | Ph.D | Semnan University, Semnān

P, Se-codoped g-C3N4 (PSeCN) nanosheet was in situ prepared by facile thermal polymerization of melamine, phosphonitrilic chloride trimer, and selenium black powder as the precursors.

The ionization and polymerization of phosphonitrilic

adshelp[at]cfa.harvard.edu The ADS is operated by the Smithsonian Astrophysical Observatory under NASA Cooperative Agreement NNX16AC86A

SDS of Phosphonitrilic chloride trimer, Safety Data Sheets

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Ultralong room temperature phosphorescence from amorphous

PVA-100-.5mg; 249.69 a.u., 0.75 s, and 9.18% for PVA-100-1mg; 315.47 a.u., 0.71 s, and 11.23% for PVA-100-3mg; 175.09 a.u., 0.69 s, and 5.51% for PVA-100-5mg; and 35

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Synonyms: Hexachlorocyclotriphosphazene , Cyclic Phosphonitrilic Chloride Trimer 4. FIRST-AID MEASURES Inhalation: Immediately call a poison center or doctor. Effects of exposure (inhalation) to substance may be delayed. Move victim to fresh air. Give artificial respiration if victim is not breathing. Administer oxygen if breathing is difficult.

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